You can use a thermistor to both heat the solution sample and test the temperature. Or use a separate heater and still use a thermistor sensor. Heat the fluid while monitoring temperature. As you approach boiling the rate of temperature rise will slow and then stop at the boiling point. You should be able to determine the boiling point to under 1 degree C this way (depending on how you measure the (sensor) and this has the added advantage of being able to stop the heating as soon as boiling point is reached. If the non-linear change of resistance is too hard to handle you can use a platinum PT100 resistor which has a very standardised linear change of resistance with temperature. You could also cheat by using one of the digital temperature measuring ic's that are available. When heating you want to keep the sample small so the heater can bring it to boiling essentially all at once. I have seen brake fluid boiling point testers which seem to work much along the above lines. From: PHXSYS Subject: HOW TO MEASURE BOILING POINT >I need some ideas for measuring the boiling point of various fluids. The >specific gravity of one fluid is approx 1.03, very close to water. The >accuracy I am looking for is +/- 3 %. I am looking for creative options, the >simplier the better.